We present experimental evidence and a corresponding theory for the ferroel
ectric transition in the family of quasi-one-dimensional conductors (TMTTF)
(2)X. We interpret this new transition in the frame of the combined Mott-Hu
bbard state taking into account the double action of the spontaneous charge
disproportionation on the TMTTF molecular stacks and of the X anionic pote
ntials.