Triazolinyl-controlled radical polymerization as innovative route to poly(hydroxyethyl methacrylate)

Authors
Dasgupta, A Brand, T Klapper, M Mullen, KR
Citation
A. Dasgupta et al., Triazolinyl-controlled radical polymerization as innovative route to poly(hydroxyethyl methacrylate), POLYM BULL, 46(2-3), 2001, pp. 131-138
Citations number
17
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
POLYMER BULLETIN
ISSN journal
01700839 → ACNP
Volume
46
Issue
2-3
Year of publication
2001
Pages
131 - 138
Database
ISI
SICI code
0170-0839(200104)46:2-3<131:TRPAIR>2.0.ZU;2-D
Abstract
2,2 ' -Azoisobutyronitril (AIBN) initiated radical polymerization of trimet hylsilyloxyethyl methacrylate (TMS-HEMA) was carried out in N,N-dimethylfor mamide (DMF) with the triazolinyl radical (T .) as additive. The latter eff ected a controlled polymerization process at least up to 60 % monomer conve rsion. The obtained poly(TMS-HEMA) with triazolin endfunctionality was appl ied to polymerize styrene, resulting in the formation of poly(TMS-HEMA)-blo ck-polystyrene.