Epoxy-acrylic macromolecular compounds on the basis of phenol and para-alkyl substituted phenol

Authors
Cascaval, CN Rosu, D
Citation
Cn. Cascaval et D. Rosu, Epoxy-acrylic macromolecular compounds on the basis of phenol and para-alkyl substituted phenol, REV RO CHIM, 45(7-8), 2000, pp. 731-737
Citations number
12
Categorie Soggetti
Chemistry
Journal title
REVUE ROUMAINE DE CHIMIE
ISSN journal
00353930 → ACNP
Volume
45
Issue
7-8
Year of publication
2000
Pages
731 - 737
Database
ISI
SICI code
0035-3930(200007/08)45:7-8<731:EMCOTB>2.0.ZU;2-8
Abstract
Some phenolic glycidyl ethers and suitable acrylic monomers on the basis of phenol and pa,a-alkyl [-CH3, -C(CH3)(3), -C9H19] substituted phenols were synthesized and characterized. The monomers were thermally polymerized in t he presence of benzoyl peroxide. The polymerization reaction was studied by viscometry, as well as by curing process. The synthesized polymers degrade statistically by a radical mechanism. The apparent thermal stability is hi gher for para-tert-butylphenol epoxy-acrylic polymer and lower for phenol e poxy-acrylic polymer.