Crystal and molecular structure of O,O-diisopropyl acetylphosphoroamidothioate

Authors
Chekhlov, AN
Citation
An. Chekhlov, Crystal and molecular structure of O,O-diisopropyl acetylphosphoroamidothioate, RUSS J G CH, 70(11), 2000, pp. 1737-1741
Citations number
11
Categorie Soggetti
Chemistry
Journal title
RUSSIAN JOURNAL OF GENERAL CHEMISTRY
ISSN journal
10703632 → ACNP
Volume
70
Issue
11
Year of publication
2000
Pages
1737 - 1741
Database
ISI
SICI code
1070-3632(200011)70:11<1737:CAMSOO>2.0.ZU;2-O
Abstract
The structure of O,O-diisopropyl acetylphosphoroamidothioate (i-PrO)(2)P(S) NHC(O)Me was studied by single crystal X-ray diffraction. Two symmetrically independent molecules with essentially different conformations are present in the crystal. The geometric parameters of these molecules (bond lengths, bond and torsion angles) were discussed. In the crystal, these molecules a re linked in infinite chains by intermolecular hydrogen bonds N-H . . .O=C.