Novel [60]fullerene-TTF cyclohexene fused polyadducts: unprecedented tri- and tetra-Diels-Alder adducts of dimethylidene[2H]tetrathiafulvalenes with C-60

Authors
Kreher, D Liu, SG Cariou, M Hudhomme, P Gorgues, A Mas, M Veciana, J Rovira, C
Citation
D. Kreher et al., Novel [60]fullerene-TTF cyclohexene fused polyadducts: unprecedented tri- and tetra-Diels-Alder adducts of dimethylidene[2H]tetrathiafulvalenes with C-60, TETRAHEDR L, 42(20), 2001, pp. 3447-3450
Citations number
23
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON LETTERS
ISSN journal
00404039 → ACNP
Volume
42
Issue
20
Year of publication
2001
Pages
3447 - 3450
Database
ISI
SICI code
0040-4039(20010514)42:20<3447:N[CFPU>2.0.ZU;2-C
Abstract
The title compounds, which are formed in very low yields by treating 2,3-bi s(bromomethyl)tetrathiafulvalenes with naked iodide in the presence of C-60 , can be obtained in much higher yields by successive similar treatments of the major adducts produced at each step. The electrochemical properties of the unprecedented tri- and tetra-TTF/C-60 assemblies are also presented. ( C) 2001 Elsevier Science Ltd. All rights reserved.