Ordered mesoporous carbons

Citation
R. Ryoo et al., Ordered mesoporous carbons, ADVAN MATER, 13(9), 2001, pp. 677-681
Citations number
44
Categorie Soggetti
Multidisciplinary,"Material Science & Engineering
Journal title
ADVANCED MATERIALS
ISSN journal
09359648 → ACNP
Volume
13
Issue
9
Year of publication
2001
Pages
677 - 681
Database
ISI
SICI code
0935-9648(20010503)13:9<677:OMC>2.0.ZU;2-E
Abstract
Ordered mesoporous carbons have recently been synthesized using ordered mes oporous silica templates. The synthesis procedure involves infiltration of the pores of the template with appropriate carbon precursor, its carbonizat ion, and subsequent template removal. The template needs to exhibit three-d imensional pore structure in order to be suitable for the ordered mesoporou s carbon synthesis, otherwise disordered microporous carbon is formed. MCM- 48, SBA-1, and SBA-15 silicas were successfully used to synthesize carbons with cubic or hexagonal frameworks, narrow mesopore size distributions, hig h nitrogen Brunauer-Emmett-Teller (BET) specific surface areas (up to 1800 m(2) g(-1)), and large pore volumes. Ordered mesoporous carbons are promisi ng in many applications, including adsorption of large molecules, chromatog raphy, and manufacturing of electrochemical double-layer capacitors.