Photothermal methods based on IR radiometry, photopyroelectric detection an
d thermoreflectance have been applied to NiTi shape memory alloys to charac
terize the thermal properties of the as-prepared samples and to determine t
he changes of the thermal properties induced by thermal and mechanical trea
tment and cycling. Using photopyroelectric detection, the integral diffusiv
ity of the treated and non treated samples has been determined. Depth profi
les of the thermal properties of the mechanically and thermally cycled ribb
on samples were measured using photothermal radiometry. A photothermal micr
oscope based on thermoreflectance was applied to monitor the thermal proper
ties across the ribbon edge and to image the thermal and optical variations
inside a grove which had been milled into a NiTi shape memory specimen.