Mid-infrared focal plane array spectroscopic or spatial imaging of opto-the
rmal transient emission is reported. Pulsed near-surface optical heating of
arbitrary unprepared room temperature surfaces produce depth-resolved tran
sient thermal emissions in the mid-infrared chemical fingerprint spectral r
egion. Two optical configurations, both offering a significant advance in p
ulsed photothermal radiometry, may be realised: (1) an opto-thermal spectro
graph capturing entire time-resolved emission spectra with each laser excit
ation shot; and (2) an opto-thermal camera producing thermal emission trans
ient spatial line images, again, with each optical stimulus. A high-speed t
ime-gated focal plane array detector forms the centrepiece of this new inst
rumentation; its adaptation, in relation to the measurement of sequenced tr
ansient phenomena, is the subject of this paper.