THE HETEROMETALLIC CLUSTER CATALYZING COO RDINATIVE HYDROGENATION ANDISOMERIZATION PROMOTED BY OXYGEN-TRANSFER REAGENT

Authors
LI QS DING ER LIU SM YIN YQ
Citation
Qs. Li et al., THE HETEROMETALLIC CLUSTER CATALYZING COO RDINATIVE HYDROGENATION ANDISOMERIZATION PROMOTED BY OXYGEN-TRANSFER REAGENT, Gaodeng xuexiao huaxue xuebao, 18(7), 1997, pp. 1007-1011
Citations number
13
Categorie Soggetti
Chemistry
Journal title
Gaodeng xuexiao huaxue xuebao → ACNP
ISSN journal
02510790
Volume
18
Issue
7
Year of publication
1997
Pages
1007 - 1011
Database
ISI
SICI code
0251-0790(1997)18:7<1007:THCCCR>2.0.ZU;2-P
Abstract
The oxygen transfer reagent (OTR), Me3NO . 2H(2)O and PhIO, can promot e the coordinative hydrogenation and isomerization of 1-hexane catalyz ed by heterometallic carbonyl clusters, SRuCo2(CO)(9) and SeRuCo2(CO)( 9), The tetrahedral skeleton of the catalyst keeps intact in catalysis process, In methanol solution, [1-Hexene]/[Cat.]=200, [Me3NO . 2H(2)O ]/[Cat.]=4, P-H2=5.0 similar to 6.0 MPa, 60 degrees C and in 24 h are the best conditions, A plausible mechanism is given.