Qs. Li et al., THE HETEROMETALLIC CLUSTER CATALYZING COO RDINATIVE HYDROGENATION ANDISOMERIZATION PROMOTED BY OXYGEN-TRANSFER REAGENT, Gaodeng xuexiao huaxue xuebao, 18(7), 1997, pp. 1007-1011
The oxygen transfer reagent (OTR), Me3NO . 2H(2)O and PhIO, can promot
e the coordinative hydrogenation and isomerization of 1-hexane catalyz
ed by heterometallic carbonyl clusters, SRuCo2(CO)(9) and SeRuCo2(CO)(
9), The tetrahedral skeleton of the catalyst keeps intact in catalysis
process, In methanol solution, [1-Hexene]/[Cat.]=200, [Me3NO . 2H(2)O
]/[Cat.]=4, P-H2=5.0 similar to 6.0 MPa, 60 degrees C and in 24 h are
the best conditions, A plausible mechanism is given.