A VIABLE ROUTE TO EXO-2-BENZYLIMINOBORNAN-3-OL - A KEY INTERMEDIATE IN THE SYNTHESIS OF A CHIRAL AUXILIARY

Authors
MORRIS DG RYDER KS
Citation
Dg. Morris et Ks. Ryder, A VIABLE ROUTE TO EXO-2-BENZYLIMINOBORNAN-3-OL - A KEY INTERMEDIATE IN THE SYNTHESIS OF A CHIRAL AUXILIARY, Synthesis, (6), 1997, pp. 620
Citations number
23
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synthesis → ACNP
ISSN journal
00397881
Issue
6
Year of publication
1997
Database
ISI
SICI code
0039-7881(1997):6<620:AVRTE->2.0.ZU;2-A
Abstract
A new synthesis of the title compound 2 has been achieved in which ben zylamine reacts with the never hydroxy N'-nitroimine 6 with concomitan t evolution of nitrous oxide, whereas the published reaction between b enzylamine and the corresponding ketone 4 does noe occur reproducibly.