The dry reforming of methane at elevated pressure over supported molybdenum
carbide catalysts, prepared from oxide precursors using ethane TPR. has be
en studied. The relative stability of the catalysts is Mo2C/Al2O3 > Mo2C/Zr
O2 > Mo2C/SiO2 > Mo2C/TiO2 and calcination of the oxide precursor for short
periods was found to be beneficial to the catalyst stability. Although the
support appears to play no beneficial role in the methane dry reforming re
action. the alumina-supported material was stable for long periods of time;
this may be important for the production of pelletised industrial catalyst
s. The evidence suggests that the differences in the stabilities may be due
to interaction at the precursor stage between MoO3 and the support. while
catalyst deactivation is due to oxidation of the carbide to MoO2, which is
inactive for methane dry reforming.