Polaronic effect fs important in the current researches on quantum dots (QD
). This paper reported a new concept of the "confined polaron", their size
dependent formation possibilities and energy variation in different QD syst
ems, with an indication of contribution from both intrinsic and/or extrinsi
c phonons, To understand the spectroscopic characteristics of porous silico
n (PS), we find that luminescence behavior of oxidized porous silicon fs in
good agreement with the model of interfacial confined polaron in QDs. This
conclusion is useful to unveiling the mechanmism of PS luminescence.