The directions of preferential growth of free-standing optical-quality CVD
diamond wafers have been investigated with the help of electron paramagneti
c resonance (EPR). EPR signals of the well-known P1 centre (substitutional
nitrogen) have been used as a probe. A computer simulation of EPR spectra o
f preferentialty oriented polycrystalline material allows the estimation of
the real orientation and spatial distribution of crystallographic axes of
crystallites in the samples oriented preferentially in the [110] direction.
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