Predictive use of a SAFT EOS for phase equilibria of some hydrocarbons andtheir binary mixtures

Citation
S. Benzaghou et al., Predictive use of a SAFT EOS for phase equilibria of some hydrocarbons andtheir binary mixtures, FLU PH EQUI, 180(1-2), 2001, pp. 1-26
Citations number
61
Categorie Soggetti
Physical Chemistry/Chemical Physics","Chemical Engineering
Journal title
FLUID PHASE EQUILIBRIA
ISSN journal
03783812 → ACNP
Volume
180
Issue
1-2
Year of publication
2001
Pages
1 - 26
Database
ISI
SICI code
0378-3812(20010415)180:1-2<1:PUOASE>2.0.ZU;2-D
Abstract
A systematic study of several hydrocarbons with a SAFT equation of state (E OS) is presented. First, it is shown that the phase behavior of the whole f amily of n-alkanes may be represented with the use of only three parameters . The approach is then extended to moderately branched alkanes, alkenes and ring compounds using one additional property, namely normal boiling point. Binary mixtures are also investigated and reasonable results are obtained with no additional binary parameters. (C) 2001 Elsevier Science B.V. All ri ghts reserved.