Planar chiral derivatives of 1,1 '-diphosphaferrocene with potential application in nonlinear optics

Authors
Klys, A Zakrzewski, J Nakatani, K Delaire, JA
Citation
A. Klys et al., Planar chiral derivatives of 1,1 '-diphosphaferrocene with potential application in nonlinear optics, INORG CH C, 4(4), 2001, pp. 205-207
Citations number
22
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANIC CHEMISTRY COMMUNICATIONS
ISSN journal
13877003 → ACNP
Volume
4
Issue
4
Year of publication
2001
Pages
205 - 207
Database
ISI
SICI code
1387-7003(200104)4:4<205:PCDO1'>2.0.ZU;2-Q
Abstract
Planar chiral "push-pull" derivatives of I,1 ' -diphosphaferrocene were obt ained in the Knoevenagel reaction starting from racemic or optically resolv ed 2-formyl-3,3 ' ,4,4 ' -tetramethyl-1,1 ' -diphosphaferrocene. Their seco nd-order non-linear optical (NLO) properties were studied by powder tests a nd the EFISHG technique at 1.907 mum. (C) 2001 Elsevier Science B.V. All ri ghts reserved.