Citation
G. Della Sala et al., The first application of titanocenes in the asymmetric oxidation of sulfides, J MOL CAT A, 170(1-2), 2001, pp. 219-224
Citations number
28
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
ISSN journal
13811169
→ ACNP
Volume
170
Issue
1-2
Year of publication
2001
Pages
219 - 224
Database
ISI
SICI code
1381-1169(20010514)170:1-2<219:TFAOTI>2.0.ZU;2-1
Abstract
Investigations were carried out on the oxidation of sulfides to sulfoxides
catalyzed by the commercial Cp2Ti(X)(2) (X=Cl, OTf)/t-butyl hydroperoxide (
TBHP). The asymmetric version of prochiral sulfides oxidation was achieved
using Cp2TiCl2, as transition metal catalyst, in the presence of (+)-(R)-BI
NOL, as chiral ligand and activated 4 Angstrom molecular sieves (m.s.). (C)
2001 Elsevier Science B.V. All rights reserved.