Citation
Jw. Huang et al., The catalysis of some novel polystyrene-supported porphyrinatomanganese(III) in hydroxylation of cyclohexane with molecular oxygen, J MOL CAT A, 170(1-2), 2001, pp. 261-265
Citations number
21
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
ISSN journal
13811169
→ ACNP
Volume
170
Issue
1-2
Year of publication
2001
Pages
261 - 265
Database
ISI
SICI code
1381-1169(20010514)170:1-2<261:TCOSNP>2.0.ZU;2-#
Abstract
Some novel polystyrene-supported porphyrinatomanganese(III) in which alkyl
group is bonded to the surface of polystyrene, PS-[Mn(HPTPP)Cl] (CnH2n+1) (
n = 2, 6, 8, 18), have been synthesized. Their catalytic activities to hydr
oxylate cyclohexane in PS-[Mn(HPTPP)Cl] (CnH2n+1)-O-2-ascrobate system have
been found to be higher compared with corresponding non-supported porphyri
natomanganese(III) and increase with the increase of the length of alkyl. T
hese results are discussed in the point of view of metalloporphyrin microen
vironment. (C) 2001 Elsevier Science B.V. All rights reserved.