Synthesis and spectral characterisation of organotin(IV) 1,3,5-triazine-2,4,6-trithiolato complexes, including the crystal structures of 1,3,5-(R3Sn)(3)C3N3S3 (R = Me, Ph)

Authors
Haiduc, I Mahon, MF Molloy, KC Venter, MM
Citation
I. Haiduc et al., Synthesis and spectral characterisation of organotin(IV) 1,3,5-triazine-2,4,6-trithiolato complexes, including the crystal structures of 1,3,5-(R3Sn)(3)C3N3S3 (R = Me, Ph), J ORGMET CH, 627(1), 2001, pp. 6-12
Citations number
26
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
JOURNAL OF ORGANOMETALLIC CHEMISTRY
ISSN journal
0022328X → ACNP
Volume
627
Issue
1
Year of publication
2001
Pages
6 - 12
Database
ISI
SICI code
0022-328X(20010504)627:1<6:SASCOO>2.0.ZU;2-G
Abstract
Novel organotin(IV) 1,3,5-triazine-2,4,6-trithiolato complexes: (R3Sn)(3)C3 N3S3, (R = Ph, Bz, Me, Bu) and (R2Sn)(3)(C3N3S3)(2), (R = Ph, Me) have been prepared and characterised by elemental analysis, FT-IR, Mossbauer and mul tinuclear NMR spectroscopy. The crystal and molecular structures of 1,3,5-( R3Sn)(3)C3N3S3 (R = Me, Ph) have been determined and contain tetrahedral or ganotin units in a 'manxane' arrangement about the central triazine. There are no close intermolecular interactions. (C) 2001 Elsevier Science B.V. Al l rights reserved.