A simple access to palladium complexes of functionalized heterocyclic carbenes

Citation
H. Glas et al., A simple access to palladium complexes of functionalized heterocyclic carbenes, J ORGMET CH, 626(1-2), 2001, pp. 100-105
Citations number
40
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
JOURNAL OF ORGANOMETALLIC CHEMISTRY
ISSN journal
0022328X → ACNP
Volume
626
Issue
1-2
Year of publication
2001
Pages
100 - 105
Database
ISI
SICI code
0022-328X(20010430)626:1-2<100:ASATPC>2.0.ZU;2-M
Abstract
Methylation of 2-(1-imidazolyl)cyclohexanol (la) and of the acylated deriva tive Ib using CH3I gives the corresponding imidazolium iodides 2a,b. These are reacted with Pd(OAc)(2) to yield the carbene complexes trans-L2PdI2 (3a ,b) bearing functionalized heterocyclic carbene ligands, which have been ch aracterized spectroscopically and by X-ray structure analysis. (C) 2001 Els evier Science B.V. All rights reserved.