Phase equilibria measurements and modeling of EPA and DHA ethyl esters in supercritical carbon dioxide

Citation
Jn. Jaubert et al., Phase equilibria measurements and modeling of EPA and DHA ethyl esters in supercritical carbon dioxide, J SUPERCR F, 20(2), 2001, pp. 145-155
Citations number
18
Categorie Soggetti
Physical Chemistry/Chemical Physics","Chemical Engineering
Journal title
JOURNAL OF SUPERCRITICAL FLUIDS
ISSN journal
08968446 → ACNP
Volume
20
Issue
2
Year of publication
2001
Pages
145 - 155
Database
ISI
SICI code
0896-8446(200106)20:2<145:PEMAMO>2.0.ZU;2-2
Abstract
A high pressure, variable-volume visual cell was used to perform static mea surements of phase equilibria involving carbon dioxide and two different fa tty acid ethyl esters: eicosapentaenoic acid (EPA) and docosahexaenoic acid (DHA) ethyl esters. Six temperatures ranging from 303.15 to 353.15 K were selected. In a second step, our data were compared with predictions obtaine d by two group contribution based models previously published. Both models are able to predict with quite high accuracy our data whatever the temperat ure. (C) 2001 Elsevier Science B.V. All rights reserved.