Conversion of homochiral amines, beta-amino alcohols and alpha-amino acidsto their chiral 2-substituted pyrrole derivatives

Authors
Demir, AS Akhmedov, IM Sesenoglu, O Alpturk, O Apaydin, S Gercek, Z Ibrahimzade, N
Citation
As. Demir et al., Conversion of homochiral amines, beta-amino alcohols and alpha-amino acidsto their chiral 2-substituted pyrrole derivatives, J CHEM S P1, (10), 2001, pp. 1162-1167
Citations number
34
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1
ISSN journal
14727781 → ACNP
Issue
10
Year of publication
2001
Pages
1162 - 1167
Database
ISI
SICI code
1472-7781(2001):10<1162:COHABA>2.0.ZU;2-4
Abstract
The conversion of the amino group of chiral amines, amino alcohols, amino a cids and their esters into chiral 2-substituted pyrrole derivatives with va rious halogeno enones is described. The conversion works in good yield and without racemization. The synthesis of 2-phenylpyrrole derivatives was poss ible with amino alcohols but not with amino acids or their esters.