Convenient synthesis of optically active 1,2-diol monosulfonates and terminal epoxides via oxazaborolidine-catalyzed asymmetric borane reduction of alpha-sulfonyloxy ketones

Authors
Cho, BT Yang, WK Choi, OK
Citation
Bt. Cho et al., Convenient synthesis of optically active 1,2-diol monosulfonates and terminal epoxides via oxazaborolidine-catalyzed asymmetric borane reduction of alpha-sulfonyloxy ketones, J CHEM S P1, (10), 2001, pp. 1204-1211
Citations number
79
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1
ISSN journal
14727781 → ACNP
Issue
10
Year of publication
2001
Pages
1204 - 1211
Database
ISI
SICI code
1472-7781(2001):10<1204:CSOOA1>2.0.ZU;2-N
Abstract
A very convenient asymmetric synthesis of 1,2-diol monosulfonates and termi nal epoxides with high optical purity via oxazaborolidine-catalyzed asymmet ric borane reduction of alpha -sulfonyloxy ketones using N-ethyl-N-isopropy laniline-borane complex as borane carrier has been developed.