1,2-Bis[(2-dimethylamino-2-thioxo-1-phenylethylidene)hydrazino]ethane: a new tetradentate ligand for Ni2+

Citation
Jd. Charrier et al., 1,2-Bis[(2-dimethylamino-2-thioxo-1-phenylethylidene)hydrazino]ethane: a new tetradentate ligand for Ni2+, J CHEM S P1, (10), 2001, pp. 1212-1215
Citations number
24
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1
ISSN journal
14727781 → ACNP
Issue
10
Year of publication
2001
Pages
1212 - 1215
Database
ISI
SICI code
1472-7781(2001):10<1212:1AN>2.0.ZU;2-#
Abstract
The preparation of a new type of N2S2 tetradentate ligand 3 with the bis(hy drazonothioamide) structure is reported in this paper. The key step in this synthesis is the condensation of the dihydrazine 7 with an alpha -ketoeste r. Ligand {1,2-bis[(2-dimethylamino-2-thioxo-1-phenylethylidene)hydrazino]e thane} 3 was obtained in 6 steps from secondary amine. This ligand is then used in the preparation of a nickel(II) complex 4 and the mesomeric forms o f metallic complex NiN2S2 are discussed.