Mechanism of the reaction of xenon tetraoxide with hydrogen: A photochemical reaction

Authors
Aleinikov, NN Vasil'ev, GK Kashtanov, SA Makarov, EF Chernyshev, YA
Citation
Nn. Aleinikov et al., Mechanism of the reaction of xenon tetraoxide with hydrogen: A photochemical reaction, KINET CATAL, 42(2), 2001, pp. 233-237
Citations number
10
Categorie Soggetti
Physical Chemistry/Chemical Physics","Chemical Engineering
Journal title
KINETICS AND CATALYSIS
ISSN journal
00231584 → ACNP
Volume
42
Issue
2
Year of publication
2001
Pages
233 - 237
Database
ISI
SICI code
0023-1584(200103/04)42:2<233:MOTROX>2.0.ZU;2-E
Abstract
The dependence of the rate of a photochemical reaction of XeO4 with H-2 On the concentrations of H2 and the diluent gases He and CO2 is studied at roo m temperature. The results are compared with the data for the dark reaction . A mechanism with the elementary energetic branched-chain reaction OH(v) XeO4 --> OH + O + XeO3 is proposed to explain the results of the study.