Conditions favorable for liquid droplet appearance on the surface of GaN ca
n be predicted for metal-organic vapor phase epitaxy and for thermal anneal
ing of the crystal in a nitrogen or hydrogen atmosphere. A critical issue o
f the model is accounting for the specific kinetics of N-2 and NH3 adsorpti
on/desorption on a nitride surface. H-2 is found to lower considerably GaN
thermal stability, in good agreement with experimental observations. The th
eoretical results are compared with available experimental data. (C) 2001 E
lsevier Science B.V. All rights reserved.