Three types of mineralisation are present in the phosphate ore mined by Ser
rana in Araxa, Brazil: oxidised, micaceous and silicate-carbonate. The mica
ceous and silicate-carbonate are considered problem ores. This investigatio
n deals with characterisation and fundamental studies performed on fraction
s resulting from the purification of five samples from the silicate-carbona
te type collected in the mine, representing portions with visually differen
t aspects, designated as: barite, carbonatite, green micaceous, brown-green
micaceous and brown clay. Each type was purified in the laboratory and the
n submitted to mineralogical characterisation, zeta potential determination
s, and microflotation experiments with anionic and cationic collectors. The
samples, with the exception of the barite, are mineralogically complex and
the selectivity between apatite and the gangue minerals is poor. The only
feasible route for processing the silicate-carbonate ore is blending it wit
h the standard oxidised ore. (C) 2001 Elsevier Science Ltd. All rights rese
rved.