A special gas analysis system has been constructed to analyze compounds cre
ated in electron avalanches in gaseous radiation detectors during their ope
ration. The analysis method is based on utilisation of cryogenic concentrat
ion unit connected to a tandem gas chromatograph and a mass spectrometer. T
he system has been designed for quantitative analysis of organic compounds
potentially involved in ageing processes of detectors. It can be exploited
to identify compounds prone to polymerise and to measure variation of compo
unds as a function of detector construction materials and additives in the
gas mixture. As a quantitative instrument it can be used to measure depende
nce of concentration of compounds on operating parameters of detectors, e.g
, gas amplification and irradiation rate and type. (C) 2001 Elsevier Scienc
e B.V. All rights reserved.