Asymmetric intramolecular C-H insertions of aryldiazoacetates

Authors
Davies, HML Grazini, MVA Aouad, E
Citation
Hml. Davies et al., Asymmetric intramolecular C-H insertions of aryldiazoacetates, ORG LETT, 3(10), 2001, pp. 1475-1477
Citations number
19
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANIC LETTERS
ISSN journal
15237060 → ACNP
Volume
3
Issue
10
Year of publication
2001
Pages
1475 - 1477
Database
ISI
SICI code
1523-7060(20010517)3:10<1475:AICIOA>2.0.ZU;2-E
Abstract
[GRAPHICS] The enantioselectivity of Rh-2(SDOSP)(4) catalyzed C-H insertion of aryldia zoacetates is very dependent on the site of the C-H insertion. The highest enantioselectivity is obtained for insertion into methine C-H bonds.