M. Ejaz et al., Controlled grafting of a well-defined polymer on a porous glass filter by surface-initiated atom transfer radical polymerization, POLYMER, 42(16), 2001, pp. 6811-6815
The atom transfer radical polymerization (ATRP) technique using the copper
halide/sparteine complexes was applied to the graft polymerization of methy
l methacrylate on a porous glass filter on which the initiator, 2-(4-chloro
sulfonylphenyl) ethyltrichlorosilane, was immobilized by chemisorption. The
graft chains were cleaved from the glass filter by the HF treatment in the
presence of a phase transfer catalyst. Gel permeation chromatographic and
infrared absorption spectroscopic measurements confirmed that the polymeriz
ation carried out in the presence of the free (sacrificing) initiator, p-to
luenesulfonyl chloride, afforded a graft layer of well-controlled, low-poly
dispersity polymer on the inner surface of the porous glass filter. The num
ber-average molecular weight (M-n) of the graft polymer increased with reac
tion time, and it was nearly equal to the M-n of the free polymer produced
in the solution. The graft density on the inner surface of the porous glass
filter was as high as those formed on a silicon wafer and a silica particl
e under similar conditions. (C) 2001 Elsevier Science Ltd. All rights reser
ved.