A new diamine monomer containing cyano group, 2-cyano-4,4 ' -diaminodipheny
l ether, was synthesized and polymerized to polyimides with several aromati
c dianhydrides via two kinds of imidization methods, namely, thermal or sol
ution imidization methods. By the thermal imidization method, tough, flexib
le, and creasable polyimide films were obtained except the polyimide from p
yromellitic dianhydride. The polyimides have high T-g values and are stable
up to 500 degreesC in air. The polyimide made from the diamine and I,4 ' -
oxyphthalic anhydride via solution imidization method was partially soluble
in polar aprotic solvents, but it becomes soluble when the cyano groups ar
e hydrolyzed.