Cooperative bimetallic oxidative addition reactions

Authors
Qin, CJ Gavrilova, A Bosnich, B
Citation
Cj. Qin et al., Cooperative bimetallic oxidative addition reactions, PUR A CHEM, 73(2), 2001, pp. 221-226
Citations number
13
Categorie Soggetti
Chemistry
Journal title
PURE AND APPLIED CHEMISTRY
ISSN journal
00334545 → ACNP
Volume
73
Issue
2
Year of publication
2001
Pages
221 - 226
Database
ISI
SICI code
0033-4545(200102)73:2<221:CBOAR>2.0.ZU;2-I
Abstract
The factors that control the oxidation of metals in bimetallic complexes ar e investigated in relation to the possibility of developing one-site additi on two-metal oxidation reactions such as those that occur in the respirator y protein, hemerythrin. It is shown that the behavior of bimetallic complex es is not represented by the sum of thr analogous monometallic parts becaus e of metal and ligand interactions.