We demonstrate via measurement of normal-incidence, near-resonant, angular
dependent second harmonic generation a strong change of Si(111)7 x 7 surfac
e symmetry as a consequence of submonolayer adsorption of sodium atoms. The
results are interpreted by assuming that a new surface structure with lowe
r symmetry coexists on the Na/Si(111)7 x 7 interface with the Sm-symmetry o
f the clean Si(111) surface. This new surface structure could be due to an
Na-induced surface reconstruction. (C) 2001 Elsevier Science Ltd. All right
s reserved.