Synthesis of the C15-C27 portion of venturicidins: a formal total synthesis of venturicidin X

Authors
Tsunashima, K Ide, M Kadoi, H Hirayama, A Nakata, M
Citation
K. Tsunashima et al., Synthesis of the C15-C27 portion of venturicidins: a formal total synthesis of venturicidin X, TETRAHEDR L, 42(21), 2001, pp. 3607-3611
Citations number
40
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON LETTERS
ISSN journal
00404039 → ACNP
Volume
42
Issue
21
Year of publication
2001
Pages
3607 - 3611
Database
ISI
SICI code
0040-4039(20010521)42:21<3607:SOTCPO>2.0.ZU;2-Y
Abstract
The C15-C27 portion of venturicidin X was prepared using substitution react ions of alkyl trifluoromethanesulfonates with a vinylmetal compound followe d by homogeneous hydrogenation. Together with our previous synthesis of the C1-C14 portion of venturicidin X, a formal total synthesis of venturicidin X was completed. (C) 2001 Elsevier Science Ltd. All rights reserved.