In biofilms, flocs and similar multispecies microbial communities, exopolys
accharides (EPSs) are always present, frequently as the major component oth
er than water. The EPSs vary widely in their composition, structure and pro
perties and thus it is impossible to generalise about their contribution to
biofilm or floc structure. Relatively few of the polymers obtained from bi
ofilms and flocs have been adequately purified and analysed but such eviden
ce as is so far available suggests that the polysaccharides closely resembl
e those synthesised by the corresponding planktonic bacteria. From a knowle
dge of the physical properties of these, if is now possible to present a re
asonably accurate picture of some of the factors which they may contribute
to the structure and stability of complex aggregates of micro-organisms in
biofilms and flocs.