STUDIES ON COMPATIBILIZATION OF POLYPROPYLENE THERMOPLASTIC POLYURETHANE BLENDS AND MECHANISM OF COMPATIBILIZATION

Citation
T. Tang et al., STUDIES ON COMPATIBILIZATION OF POLYPROPYLENE THERMOPLASTIC POLYURETHANE BLENDS AND MECHANISM OF COMPATIBILIZATION, Journal of macromolecular science. Physics, B33(3-4), 1994, pp. 287-305
Citations number
10
Categorie Soggetti
Polymer Sciences
ISSN journal
00222348
Volume
B33
Issue
3-4
Year of publication
1994
Pages
287 - 305
Database
ISI
SICI code
0022-2348(1994)B33:3-4<287:SOCOPT>2.0.ZU;2-S
Abstract
This paper reports a study of compatibilization and the mechanism of c ompatibilization of polypropylene (PP)/thermoplastic polyurethane (TPU ) blends with maleated polypropylene (PP-MA) and its graft copolymer w ith polyethylene oxide (PEO), (PP-MA)-g-PEO. The results of scanning e lectron microscope (SEM) and dynamic mechanical analysis showed that ( PP-MA)-g-PEO was a very good compatibilizer for PP/TPU blends, while P P-MA also produced some compatibilization. The cocrystallization betwe en bulk PP and PP segments of the compatibilizers was evidenced by dif ferential scanning calorimetry studies. The specific interaction betwe en TPU and polar parts of the compatibilizers was studied with Fourier transform infrared spectroscopy.