trans-bis(hexafluoroantimonato)-(phthalocyaninato)copper(II)

Authors
Gardberg, AS Ibers, JA
Citation
As. Gardberg et Ja. Ibers, trans-bis(hexafluoroantimonato)-(phthalocyaninato)copper(II), ACT CRYST C, 57, 2001, pp. 528-529
Citations number
10
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
57
Year of publication
2001
Part
5
Pages
528 - 529
Database
ISI
SICI code
0108-2701(200105)57:<528:T>2.0.ZU;2-Z
Abstract
The title compound, trans-bis(hexafluoroantimonato-F)-(phthalocyaninato-kap pa N-4(29,30,31,32))copper(II), [Cu(SbF6)(2)(C-32-H16N8)] or Cu(pc)(SbF6)(2 ) (pc is phthalocyaninate), comprises a six-coordinate Cu atom, lying on an inversion center, bonded to four N atoms of a phthalocyanine ring and to F atoms of two trans SbF6- groups. The compound is presumed to consist of a Cu-II center and a doubly oxidized phthalocyanine ring, by analogy with Cu( pc)(ReO4)(2).