Anhydrous lead(II) heptanoate

Citation
F. Lacouture et al., Anhydrous lead(II) heptanoate, ACT CRYST C, 57, 2001, pp. 530-531
Citations number
10
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
57
Year of publication
2001
Part
5
Pages
530 - 531
Database
ISI
SICI code
0108-2701(200105)57:<530:ALH>2.0.ZU;2-6
Abstract
The title compound, catena-poly[[(heptanoato-O,O')lead(II)]-mu -heptanoato- O,O' :O:O'], [Pb(C7H13O2)(2)], is a metallic soap which can be used as a co rrosion inhibitor since it forms a passive film at the Pb surface. Its stru cture is characterized by two-dimensional layers parallel to the bc plane. The layers are packed through van der Waals interactions along the a direct ion and form blocks parallel to (001). The 6s(2) lone pair of electrons on Pb-II is stereochemically active in this compound, which leads to a hemidir ected octahedral geometry for the O-environment around the Pb atoms.