Citation
Sg. Fontan et al., Tetracarbonyl(diphenyldithio-phosphinato-S,S ')rhenium(I), ACT CRYST C, 57, 2001, pp. 532-533
Citations number
18
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701
→ ACNP
Volume
57
Year of publication
2001
Part
5
Pages
532 - 533
Database
ISI
SICI code
0108-2701(200105)57:<532:T'>2.0.ZU;2-L
Abstract
The title compound consists of [Re(C12H10PS2)(CO)(4)] molecules in which th
e Re atom is octahedrally coordinated by four carbonyl groups and two dithi
ophosphinate S atoms. The main coordination distortion is imposed by the li
gand bite angle of 78.29 (4)degrees. The bidentate coordination of the dith
iophosphinate ligand involves almost equal Re-S [2.5366 (15) and 2.5535 (14
) Angstrom] and P-S distances [2.0100 (19) and 2.0212 (19) Angstrom].