trans-diiodobis(1,3,5-triaza-7-phosphaadamantane)platinum(II)

Authors
Otto, S Roodt, A
Citation
S. Otto et A. Roodt, trans-diiodobis(1,3,5-triaza-7-phosphaadamantane)platinum(II), ACT CRYST C, 57, 2001, pp. 540-541
Citations number
21
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
57
Year of publication
2001
Part
5
Pages
540 - 541
Database
ISI
SICI code
0108-2701(200105)57:<540:T>2.0.ZU;2-K
Abstract
The crystal structure of the title compound, trans-[PtI2- (C6H12N3P)(2)], d escribes one of the few platinum(II) complexes containing two of the water- soluble 1,3,5-triaza-7-phosphaadamantane ligands reported to date. The comp lex crystallizes on an inversion centre with the most important bond length s and angles being Pt-P 2.3128 (12) Angstrom, Pt-I 2.6022 (6) Angstrom, P-P t-I 90.94 (3)degrees and P'-Pt-I 89.06 (3)degrees.