The title compound, [Fe-3 (C5H11NO2)(6)O(H2O)(3)](MnCl4)(2)Cl-3. 6H(2)O, co
ntains a triiron core linked by a mu (3)-bridging oxide ion. Each of the ir
on(III) ions has a distorted octahedral environment, being coordinated, in
addition to the oxide ion, by four neutral betaine molecules and one water
molecule. The N-alkylated alpha -amino acid betaine is present in the dipol
ar zwitterionic form and chelates pairs of Fe atoms at the vertices of the
triangular [Fe3O](7+) ionic core. The Fe complex has a crystallographically
imposed D3 symmetry. The water molecules fully exhaust their potential as
hydrogen donors, forming a two-dimensional hydrogen-bond network in planes
parallel to (001).