Model-based methods for clustering artefacts, given their chemical composit
ion, often assume sampling from a mixture of multivariate normal distributi
ons and/or make explicit assumptions about the way in which a composition i
s formed. It is argued that, analysed within a modelling framework, several
important and apparently competing methodologies are more similar than wou
ld initially appear. The opportunity is taken to note that models for popul
ations are often not compatible with models for compositions, and that dilu
tion correction--which can be accomplished in a variety of ways--can be int
erpreted as an attempt to resolve this problem.