A new model for the substitution patterns in the polymer chain of polysaccharide derivatives

Authors
Mischnick, P Hennig, C
Citation
P. Mischnick et C. Hennig, A new model for the substitution patterns in the polymer chain of polysaccharide derivatives, BIOMACROMOL, 2(1), 2001, pp. 180-184
Citations number
20
Categorie Soggetti
Biochemistry & Biophysics","Organic Chemistry/Polymer Science
Journal title
BIOMACROMOLECULES
ISSN journal
15257797 → ACNP
Volume
2
Issue
1
Year of publication
2001
Pages
180 - 184
Database
ISI
SICI code
1525-7797(200121)2:1<180:ANMFTS>2.0.ZU;2-M
Abstract
A new mathematical model is presented for the analysis of the substituent d istribution in the polymer chain of polysaccharide derivatives. For the fir st time, the influence of substitution on the reactivity of neighbored mono mer units is taken into account. The model was applied to various cellulose and amylose ethers and esters and excellently fits the experimental data.