Surface electrical potential of yttria-doped zirconia (10 mol%) uas monitor
ed using work function measurements in contact with gas phase of controlled
oxygen partial pressure during heating and cooling at different rates in t
he temperature range 298-1173 It. The WF vs. temperature characteristics in
dicate that the oxygen/zirconia system assumes equilibrium above 1000 K. Th
e effect of temperature on WF data is considered in terms of both oxygen ch
emisorption on zirconia and electronic structure of zirconia.