Thermodynamic evaluation and optimization of the LiCl-NaCl-KCl-RbC1-CsC1-MgCl2-CaCl2-SrC2-BaCl2 system using the modified quasichemical model

Authors
Chartrand, P Pelton, AD
Citation
P. Chartrand et Ad. Pelton, Thermodynamic evaluation and optimization of the LiCl-NaCl-KCl-RbC1-CsC1-MgCl2-CaCl2-SrC2-BaCl2 system using the modified quasichemical model, CAN METAL Q, 40(1), 2001, pp. 13-32
Citations number
54
Categorie Soggetti
Metallurgy
Journal title
CANADIAN METALLURGICAL QUARTERLY
ISSN journal
00084433 → ACNP
Volume
40
Issue
1
Year of publication
2001
Pages
13 - 32
Database
ISI
SICI code
0008-4433(200101)40:1<13:TEAOOT>2.0.ZU;2-1
Abstract
All available phase diagram and thermodynamic data for BaCl2 containing sub systems of the LiCl-NaCl-KCl-RbCl-CsCl-MgCl2-CaCl2 SrCl2 BaCl2 system were critically evaluated and optimized. The modified quasichemical model for sh ort-range ordering was used for the liquid phase, The model parameters obta ined for the binary and ternary subsystems, combined with similar parameter s obtained in previous optimizations of subsystems without BaCl2, can be us ed to predict the thermodynamic properties and phase equilibria of the nine -component system.