Evolution of microstructure and morphology of Co3O4 particles in the model
systems during reduction in hydrogen was studied by transmission electron m
icroscopy methods. Based on SAED and HRTEM results we found that the degree
of reduction of Co3O4 strongly depends on the particle size and morphology
, which are determined by the pretreatment conditions. Preferential epitaxi
al growth of CoO and Co phases on Co3O4 during reduction was deduced from H
RTEM images.