Catalytic epoxidation of styrene over copper hydroxyphosphate Cu-2(OH)PO4

Citation
Xj. Meng et al., Catalytic epoxidation of styrene over copper hydroxyphosphate Cu-2(OH)PO4, CATAL LETT, 71(3-4), 2001, pp. 241-244
Citations number
7
Categorie Soggetti
Physical Chemistry/Chemical Physics","Chemical Engineering
Journal title
CATALYSIS LETTERS
ISSN journal
1011372X → ACNP
Volume
71
Issue
3-4
Year of publication
2001
Pages
241 - 244
Database
ISI
SICI code
1011-372X(2001)71:3-4<241:CEOSOC>2.0.ZU;2-X
Abstract
Catalytic epoxidation of styrene with hydrogen peroxide over copper hydroxy phosphate Cu-2(OH)PO4 was studied. Catalytic data shows that the catalyst C u-2(OH)PO4 is very active, and the main products are styrene epoxide and be nzaldehyde, particlularly giving high selectivity for styrene epoxide. In c ontrast, over TS-1 a large amount of phenylacetaldehyde product is formed. Some important factors associated with the catalytic activity and selectivi ty are investigated extensively.