Hydrogen bonding and CH/pi interactions for the stabilization of biomimetic zinc complexes: first examples of X-ray characterized alcohol and amide adducts to a tetrahedral dicationic Zn center

Authors
Seneque, O Giorgi, M Reinaud, O
Citation
O. Seneque et al., Hydrogen bonding and CH/pi interactions for the stabilization of biomimetic zinc complexes: first examples of X-ray characterized alcohol and amide adducts to a tetrahedral dicationic Zn center, CHEM COMMUN, (11), 2001, pp. 984-985
Citations number
13
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
11
Year of publication
2001
Pages
984 - 985
Database
ISI
SICI code
1359-7345(2001):11<984:HBACIF>2.0.ZU;2-F
Abstract
X-Ray analysis of two biomimetic (N3ZnL)(2+) complexes with L = ethanol and formamide revealed that hydrogen bonding and CH/pi interactions between th e guest ligand L and the calix[6]arene host structure play a key role in th eir stabilization.