Conformational isomerism leads to supramolecular isomerism and nanoscale inclusion in 2D extended framework solids based on C-methylcalix[4]resorcinarene

Authors
MacGillivray, LR Reid, JL Ripmeester, JA
Citation
Lr. Macgillivray et al., Conformational isomerism leads to supramolecular isomerism and nanoscale inclusion in 2D extended framework solids based on C-methylcalix[4]resorcinarene, CHEM COMMUN, (11), 2001, pp. 1034-1035
Citations number
24
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
11
Year of publication
2001
Pages
1034 - 1035
Database
ISI
SICI code
1359-7345(2001):11<1034:CILTSI>2.0.ZU;2-W
Abstract
Co-crystallization of C-methylcalix[4]resorcinarene 1 with 4,4'-bipyridine 2 in the presence of m-xylene results in the formation of a 2D brick framew ork, 3c.2(m-xylene), that possesses nanoscale cavities that host four aroma tics as guests in which 1 adopts a 'T-shaped' conformation.