The cathodic insertion of tetraalkylammonium iodides into palladium

Authors
Cougnon, C Simonet, J
Citation
C. Cougnon et J. Simonet, The cathodic insertion of tetraalkylammonium iodides into palladium, ELECTROCH C, 3(5), 2001, pp. 209-214
Citations number
20
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ELECTROCHEMISTRY COMMUNICATIONS
ISSN journal
13882481 → ACNP
Volume
3
Issue
5
Year of publication
2001
Pages
209 - 214
Database
ISI
SICI code
1388-2481(200105)3:5<209:TCIOTI>2.0.ZU;2-V
Abstract
The cathodic behavior of tetraalkylammonium iodides was studied at a polish ed palladium cathode in aprotic dimethylformamide (DMF). Coulometric and el ectrochemical quartz crystal microbalance analyses allowed to show the form ation of phases, the stoichiometry of which was fully determined. The rever sible insertion of tetraalkylammonium cations as well as the electrolyte in to palladium was demonstrated. (C) 2001 Elsevier Science B.V. All rights re served.