Experimental studies were performed to investigate the formation mechanisms
of submicrometer particles during combustion of a pulverized Ohio bitumino
us coal. Elemental compositions of total and submicrometer ash and particle
size distributions were measured at different operating conditions. The su
bmicrometer ash particles were formed by means of a vaporization-nueleation
-condensation mechanism. A decreasing collection efficiency in a cylindrica
l. electrostatic precipitator was observed for ash particles smaller than 1
00 nm due to insufficient charging. A vapor-phase sorbent injection methodo
logy was used in the coal combustion system, and was shown to suppress the
nucleation mode of the ash particles.